NICKEL BIS-TRIPHENYLPHOSPHINE DIBROMIDE

Synonyms. Nickel bis-triphenylphosphine dibromide; Bis(triphenylphosphine)nickel(II)bromide; Nickel (2+) bis(triphenylphosphine) bromide; Dibromobis(triphenylphosphine)nickel(II);

Click to see the original

 

PRODUCT IDENTIFICATION

CAS RN

14126-37-5

EINECS RN

 

FORMULA

[(C6H5)3P]2NiBr2

MOLE WEIGHT

743.07

H.S CODE

 2942.00.1000

SMILES

 C1=CC=C(C=C1)[PH+](C2=CC=CC=C2)C3=CC=CC=C3.C1=CC= C(C= C1)[PH+] (C2=CC=CC=C2)C3=CC=CC=C3.[Ni](Br)Br

CLASSIFICATION

 

EXTRA NOTES

Catalysts for the cross-coupling reactions, C-X bond reduction, homocoupling of Csp2 halides, displacement of aryl halides, and oligomerization of dienes.

 

PHYSICAL AND CHEMICAL PROPERTIES

PHYSICAL STATE.

dark green powder

MELTING POINT

219 ~ 223 C

BOILING POINT

 

DENSITY

 

SOLUBILITY IN WATER

 

SOLVENT SOLUBILITY

 

VAPOR DENSITY

 

log P(octanol-water)

  

VAPOR PRESSURE

  

AUTOIGNITION TEMP

  
pK

 

REFRACTIVE INDEX

 

FLASH POINT

 

 

STABILITY AND REACTIVITY
STABILITY Stable under normal conditions. Corrosive.

INCOMPATIBLE MATERIALS

Strong oxidizing agents, Moisture.

POLYMERIZATION

Has not been reported

NFPA RATINGS

Health: 2, Flammability: 0, Reactivity: 0

 

EXTERNAL LINKS & GENERAL DESCRIPTION

USA.gov - Nickel bis-triphenylphosphine dibromide

Google Scholar Search - Nickel bis-triphenylphosphine dibromide

PubChem Compound Summary - Nickel bis-triphenylphosphine dibromide

NCBI (http://www.ncbi.nlm.nih.gov/) -  Nickel bis-triphenylphosphine dibromide

 

SALES SPECIFICATION

APPEARANCE

dark green powder

ASSAY

99% min

MELTING POINT

219 ~ 234 C

LOSS ON DRYING

1.0% max

 

TRANSPORT & REGULATORY INFORMATION

UN NO.

1759

HAZARD CLASS

8

PACKING GROUP II

 

SAFETY INFORMATION

HAZARD OVERVIEW

GHS (Globally Harmonised System) Classification: Acute toxicity (Oral), Acute toxicity (Inhalation), Acute toxicity (Dermal). Hazard statements: Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

SIGNAL WORD Warning

PICTOGRAMS

HAZARD STATEMENTS

H302 + H312 + H332 Harmful if swallowed, in contact with skin or if inhaled

PRECAUTIONARY STATEMENTS

P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray.
P264 Wash skin thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/ protective clothing.
P301 + P312 IF SWALLOWED: Call a POISON CENTER or doctor/ physician if you feel unwell.
P302 + P352 IF ON SKIN: Wash with plenty of soap and water.
P304 + P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P312 Call a POISON CENTER or doctor/ physician if you feel unwell.
P322 Specific measures (see supplemental first aid instructions on this label).
P330 Rinse mouth.
P363 Wash contaminated clothing before reuse.
P501 Dispose of contents/ container to an approved waste disposal plant.

EC DIRECTIVES

 

HAZARD CODES

RISK PHRASES

20/21/22 Harmful by inhalation, in contact with skin and if swallowed.

SAFETY PHRASES

36/37 Wear suitable protective clothing and gloves.

 

PACKING

Preserve in light-resistant and well-closed containers

 

PRICE INFORMATION